1. 个人简介:
姓名:余焓
职称:教授
简介:余焓博士,教授,上海交通大学应用化学博士,清华大学化学系博士后;剑桥大学化学系高级访问学者,入选上海市海外高层次人才计划。一直从事催化剂的研究,涉及金属氧化物催化剂的设计与合成,精细化学品的高效催化与合成 ;环境友好的催化过程(光电热反应条件下的多/均相催化、仿生催化和环境催化), 至今以第一/通讯作者发表SCI论文50余篇,包括Angew. Chem. Int. Ed.J. Am. Chem. Soc.等。提出了“无机配体催化剂”的新理念,发展了金属氧化物均相催化的新方法,产学研方面创建了产业界少有的绿色选择性氧化反应技术中心,获得比亚迪系等多家风投机构投资,多项催化剂成果应用于工业化。
2. 研究领域:
[1] 催化剂的设计与合成
[2] 精细化学品的高效催化与合成
[3] 环境友好的催化过程(光、电、热条件下的多/均相催化、仿生催化和环境催化)
3 学术兼职
国家自然科学基金评审专家,担任ACS, Wiley, RSC, Elsevier等多个出版社的学术期刊审稿人;
4 项目与荣誉
[1] 多金属氧酸盐催化醇的选择性氧化体系构建及其在合成化学中的应用,国家自然科学基金(面上项目)2019-2022;
[2] 基于烷基硼为亲核试剂手性亚磷酰胺Cu催化的Michael反应的研究,国家自然科学基金(青年项目) 2015-2017;
[3] 第三届“海聚英才”全球创新创业大赛三等奖;
[4] HICOOL2023全球创新创业大赛二等奖;
[5] 2022年高等学校科学研究优秀成果奖二等奖,(排名第二);
[6] 第九届中国海归创业大赛优胜奖, (排名第一);
[7] 2022年上海市闵行区杰出人才(上海市闵行区委和政府);
5. 成果:
代表性论文:
[1] Han Yu*, et al.“Imparting Functionality to Nano-sized Metal-Organic Framework by Controlled Coordination of Methoxy PEG Phosphate” J. Am. Chem. Soc.2021, 143, 13557-13572.
[2] Han Yu*, et al.“Photocatalytic Dissolution of Precious Metals by TiO2 through Photogenerated Free Radicals” Angew. Chem. Int. Ed. 2022, 61, 50, e202213640.
[3] Han Yu*, et al.“Chemically Bonded Dot-on-Plate Z-Scheme Junction with Strong Interal Electric Field for Superior Upgrading Photo-oxidation of Aromatic Alcohols”Angew. Chem. Int. Ed. 2022, doi.org /10.1002/ anie. 202203519.
[4] Han Yu*, et al. “Synergistic Polarization Engineering on Bulk and Surface for Boosting CO2Photoreduction” Angew. Chem. Int. Ed. 2021,60, 18303-18308.
[5] Han Yu*, et al. “Selective oxidation of anilines to azobenzenes and azoxybenzenes by a molecular Mo oxide catalyst” Angew. Chem. Int. Ed. 2021, 60,6382-6385.
[6] Han Yu*, et al. “Light-Induced Efficient Hydroxylation of Benzene to Phenol by Quinolinium and Polyoxovanadate-based Supramolecular Catalysts”Angew. Chem. Int. Ed. 2021,60, 13310-13316.
[7] Han Yu*, et al.“An Efficient Iron(III)-Catalyzed Aerobic Oxidation of Aldehydes in Water for the Green Preparation of Carboxylic Acids” Angew. Chem. Int. Ed. 2017, 56, 3867-3871.(SCI一区,IF= 15.336)
[8] Han Yu*, et al.“Additive-Mediated Selective Oxidation of Alcohols to Esters via Synergistic Effect Using Single Cation Cobalt Catalyst Stabilized with Inorganic Ligand” Research,2020,doi.org /10.34133/2020/3875920
[9] Han Yu*, et al.“Selective iron-catalyzed aerobic oxidation of alcohols in water to carboxylic acids mediated by additives” Green Chem. 2022, 24, 6511-6516.
[10] Han Yu*, et al.“Oxidative carbon-carbon bond cleavage of 1,2-diols to carboxylic acids/ketones by an inorganic-ligand supported iron catalyst” Green Chem. 2021, 23, 9140-9146.
[11] Han Yu*, et al.“Oxidative esterification of alcohols by a single-side organically decorated Anderson-type chrome-based catalyst” Green Chem. 2021, 23, 2652-2657.
[12] Han Yu*, et al.“Transformation of Arylboronic Acids with Sodium Thiosulfate into Organodisulfides Catalyzed by Recyclable Polyoxometalate-based Green Cr(III) Catalyst” Green Chem.2021,23, 6059-6064.
[13] Han Yu*, et al.“An Efficient and Green Way for the N-Formylation of Amines by Inorganic-ligand Supported Iron Catalysis” Green Chem.2020,22, 737-741.
[14] Han Yu*, et al.“Highly Efficient Oxidation of Alcohols to Carboxylic Acids Using Polyoxometalate-supported Chromium(III) Catalyst and CO2” Green Chem.2020, 22, 3150-3154.
[15] Han Yu*, et al.“Aldehydes as potential acylating reagents for oxidative esterification by inorganic ligand supported iron catalysis” Green Chem.,2019, 21, 4550-4554.
6. 代表性授权专利:
[1] 余焓;但德敏;吴志康,《一种1,5-萘二异氰酸酯的制备方法》,ZL201910469665.X
[2] 余焓;但德敏;吴志康,《一种二甲基联苯二异氰酸酯的制备方法》,ZL201910469697.X
[3] 余焓;但德敏;吴志康,《一种4,4’-二环己基甲烷二异氰酸酯的制备方法》,ZL201910469044.1
[4] 余焓;但德敏;吴志康,《一种甲苯二异氰酸酯的制备方法》,ZL201910469661.1
[5] 余焓;但德敏;吴志康,《一种4,4’-二苯基甲烷二异氰酸酯的制备方法》,ZL201910469663.0
[6] 余焓;但德敏;吴志康,《一种异佛尔酮二异氰酸酯的制备方法》,ZL201910469696.5
[7] 余焓;程颖;胡敬;龙韬;常亚林,《7-喹啉酸配位的金属催化剂及复合物的制备方法及应用》,ZL202310730944.3
[8] 余焓;程颖;胡敬;龙韬;常亚林,《一种羟基喹啉配位的催化剂及复合物的制备方法及应用》,ZL202310730952.8
[9] 余焓;程颖;胡敬;张可;龙韬;常亚林,《6-喹啉酸配位的金属催化剂及复合物的制备方法及应用》,ZL202310730954.7
[10] 余焓;刘秦;程颖;胡敬;龙韬,《一种高纯度间甲基苯甲酸的制备系统及方法》,ZL202311140916.2